About my academic career
Country of origin: Poland
Currently working at Laboratoire d’Electrochimie Moléculaire (LEM) – Université Paris Cité, France
M. Sc. in Chemistry
University of Warsaw, Faculty of Chemistry, Poland
Specialization: Organic Synthesis, supervisor: Marcin Kalek, Ph.D. D.Sc., thesis title: Oxidative dearomatizing methoxylation of phenols under galvanostatic conditions
July – September
Max-Planck-Institute
Internship, work on Late-stage functionalization via Pd catalyzed reductive coupling in the Department of Organic Synthesis, Max-Planck Institute for Coal Research, with prof. Tobias Ritter, Mülheim an der Ruhr, Germany
B.Sc. in Chemistry
University of Warsaw, Faculty of Chemistry, Poland
supervisor: Marcin Kalek, Ph.D. D.Sc., thesis title: Synthesis of fluorescent probe for studies of NFκB pathway
Mechanism of Iodine(III)‐Promoted Oxidative Dearomatizing Hydroxylation of Phenols: Evidence for a Radical‐Chain Pathway
Karol Kraszewski, Ireneusz Tomczyk, Aneta Drabinska, Krzysztof Bienkowski, Renata Solarska, Marcin Kalek
Chem. Eur. J. 2020, 26, 11584-11592
Intermolecular enantioselective dearomatizing para-methoxylation of phenols using 2-iodoresorcinol/lactamide catalysts
Karol Kraszewski, Ireneusz Tomczyk, Marcin Kalek
Tetrahedron Lett. 2022, 108, 154127
Reductive Cross-Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides.
Beatrice Lansbergen, Srija Tewari, Ireneusz Tomczyk, Maik Seemann, Henning Louis Buchholz, Mike Rippegarten,
Daniel Chamier Cieminski, Fabio Juliá, Tobias Ritter
Angew. Chem. Int. Ed. 2023, 62, e202313659
Electrochemical Dearomatizing Methoxylation of Phenols and Naphthols: Synthetic and Computational Studies
Ireneusz Tomczyk, Marcin Kalek
Chem. Eur. J. 2024, e202303916
About my thesis - Electrochemical detection and conversion of small molecules
The activation of oxygen emerges as a prospective approach to prevailing economic challenges, given the pivotal role of oxygenation and halogenation reactions in the chemical industry. Present oxidation methodologies frequently require the use of harmful chemical oxidants or necessitate the application of extreme temperature and pressure conditions in conjunction with noble metal catalysts.
In recent years, the Laboratory of Molecular Electrochemistry has developed an innovative approach for performing mild oxidation reactions, inspired by the mechanisms observed in metalloenzymes.
This methodology combines synthetic, spectroscopic, and electrochemical techniques to mimic the catalytic functions of these enzymes. As a result, they have successfully applied this approach to carry out electrocatalytic oxygenation and chlorination of cyclooctene.
The current project is primarily focused on the further development of this methodology. Specifically, our goal is to broaden its applicability and to transfer it to green solvent solutions (e.g. water) and liquid/solid interfaces through the grafting of the catalyst onto a conductive system.